Room-temperature catalyst-free methane chlorination
Title
Room-temperature catalyst-free methane chlorination
Subject
natural gas
energy conservation
alkane chlorination
C-H activation
free radical
greenhouse gas
methanol economy
upgradation
valorization
Description
Summary The chlorination of methane presents a route for the upgrading of natural gas to value-added products. However, due to the low reactivity of methane, existing chlorination processes require the use of elevated temperatures and catalysts. Here, we report a simple process for the chlorination of methane at near-ambient temperatures using minimal reagents and no catalysts or external sources of energy. The reaction is carried out in an aqueous medium with trichloroisocyanuric acid as a chlorinating agent. The dissolution of trichloroisocyanuric acid in water leads to the sustained and buffered release of hypochlorous acid, which triggers the chlorination of methane by a free-radical mechanism. The process is also general to other alkanes, as shown by a similar chlorination of ethane. Further developments are required for this process to be deployed as a practical method of chloromethane production.
9
2
Publisher
Cell Reports Physical Science
Date
2021
2021-09-22
Contributor
Mohan, Varun
Dutta, Biswanath
Ripani, Roma
Jain, Prashant K.
Type
journalArticle
Identifier
2666-3864
10.1016/j.xcrp.2021.100545
URL
https://www.sciencedirect.com/science/article/pii/S2666386421002563
Collection
Citation
“Room-temperature catalyst-free methane chlorination,” Lamar University Midstream Center Research, accessed May 18, 2024, https://lumc.omeka.net/items/show/19252.