Pyrolytic remediation of crude oil-contaminated soil

Pyrolytic remediation of crude oil-contaminated soil

Crude oil

Pyrolysis

Efficiency

Soil

Deterioration

Contamination

Remediation

Soil pollution

Soils

Oil spills

Soil surveys

Hexane

Seed

Bentonite

Deterioration of our terrestrial environment due to decreasing soil quality brought on by crude oil spills and leakages is a major issue. In this study, soil samples were prepared by mixing clay (bentonite) and sand contaminated with 5 and 10 wt% crude oil (in order to study the effect of oil concentration), and weathered in a laboratory to simulate actual contaminated soil. Volatilization of light oil was inhibited in clay rich-soil, resulting in higher contamination after weathering. The efficiency of the pyrolytic treatment was evaluated by comparing the weight change and n-hexane extractable material (HEM) content of the soil samples. The working temperature influenced pyrolysis efficiency more than the reaction time. A residual amount of 0.29–0.61 wt% (below the soil pollution standard) was observed in the samples with high clay content and pollution level (by pyrolysis for 30 min at 400 °C). Infrared analysis of treated soil samples showed a reduction in alkyl functionality (CH), confirming a decrease in hydrophobicity and an improvement in water holding capacity (WHC). Seed germination and plant growth were relatively better in the pyrolyzed soil. The field applicability of the pyrolytic treatment process was confirmed at laboratory and pilot scale, as well as by treating soil samples collected from actual polluted sites.

136498

713

Science of The Total Environment

2020

Kang, Chan-Ung

Kim, Do-Hyeon

Khan, Moonis Ali

Kumar, Rahul

Ji, Seung-Eun

Choi, Kung-Won

Paeng, Ki-Jung

Park, Sungmin

Jeon, Byong-Hun

journalArticle

0048-9697

10.1016/j.scitotenv.2020.136498

https://www.sciencedirect.com/science/article/pii/S0048969720300061