LaNi5.5 particles for reversible hydrogen storage in N-ethylcarbazole

LaNi5.5 particles for reversible hydrogen storage in N-ethylcarbazole

Hydrogen storage

Efficiency

Binary alloys

Calcium compounds

Hydrogen storage alloys

In this work, we demonstrate that the classic hydrogen storage alloy LaNi5 can catalyze the reversible hydrogen storage in N-ethylcarbazole (NEC), one of the most promising liquid organic hydrogen carriers (LOHCs), with high efficiency and cyclic stability. Using CaH2 reduction in molten salt, uniform LaNi5+x particles around 100 nm are obtained from hydroxide precursors. The sub-m LaNi5.5 particles exhibit excellent catalytic ability for reversible hydrogen storage in NEC, which is originated from the synergism of surface excessive Ni and the LaNi5 core with reversible hydrogen storage property. Hydrogen storage capacity above 5.5 wt% H2 (based on 12 H-NEC) can be achieved for 9 cycles using 10 wt% LaNi5.5. The time required to reach 5.5 wt% hydrogen storage capacity is about 4.5 h for NEC hydrogenation at 453 K and 4.0 h for 12 H-NEC dehydrogenation at 473 K. The results are very promising in developing high-efficiency LOHC-based hydrogen storage systems and provide new insights into hydride-based catalysts. 2020 Elsevier Ltd

80

Nano Energy

2021

Yu, Hongen

Yang, Xue

Jiang, Xiaojing

Wu, Yiman

Chen, Shunpeng

Lin, Wei

Wu, Yong

Xie, Lei

Li, Xingguo

Zheng, Jie

journalArticle

22112855

10.1016/j.nanoen.2020.105476